Akazukin Chacha episode 42
The finished shield is then stolen by [Hogan] who then uses it to challenge Holy Up. Chacha transforms but cannot penetrate with her Phoenix Sword Attacks. The blacksmith, with a little persuasion from Seravi, instructs the Princess to throw the Phoenix sword at the shield. Chacha does and [Hogan] is defeated. Since the blacksmith skipped one part of the process (he forgot to include the crest of the angel of magic), the shield that he made was fake. They must continue to look for the shield.
[Akazukin Chacha TV episode guide]
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(c)Ayahana Min/Shuueisha, TV Tokyo, NAS